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Thermodynamics of equilibrium: van't Hoff equation
NEET level
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ce117
For an endothermic reaction, what happens to the equilibrium constant when the temperature is raised?
A
K
decreases
B
K
remains unchanged
C
K
increases
D
K
first increases and then decreases
Answer: C
By the van't Hoff equation,
d
T
d
ln
K
=
R
T
2
Δ
H
∘
. For an endothermic reaction
Δ
H
∘
>
0
, so
ln
K
and hence
K
rise with temperature.
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