JEE Advanced levelSingle correct optionDifficulty 3 of 3co132
Nine compounds are separately warmed with IX2/NaOH: ethanol, propan-2-ol, phenyl methyl ketone, benzaldehyde, pentan-3-one, ethanal, propanal, methanol and butan-2-one. How many give a positive iodoform test?
A3
B4
C5
D6
Answer: C
Positive: ethanol, propan-2-ol (both oxidised to CHX3COX− compounds), phenyl methyl ketone, ethanal and butan-2-one. Negative: benzaldehyde, pentan-3-one, propanal and methanol. The count is 5.