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JEE Advanced levelSingle correct optionDifficulty 3 of 3co135

How many acyclic carbonyl compounds (aldehydes and ketones, ignoring stereoisomers) of molecular formula give a positive iodoform test?

  1. A1
  2. B2
  3. C3
  4. D4

Answer: B

The isomers are 4 aldehydes and 3 ketones. Only methyl ketones respond, because no aldehyde other than ethanal does: pentan-2-one and 3-methylbutan-2-one. The answer is 2.
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