JEE Main levelOne or more correct optionsDifficulty 2 of 3co129
Which of the following give iodoform when warmed with IX2 and aqueous NaOH?
Aheptan-2-one
B1-phenylpropan-2-one, CX6HX5CHX2COCHX3
Cpentan-3-one
D1-phenylpropan-1-one, CX6HX5COCHX2CHX3
Answer: A, B
Heptan-2-one and CX6HX5CHX2COCHX3 both contain the CHX3COX− group. Pentan-3-one and propiophenone have CHX3CHX2COX− groups, whose alpha carbons are only CHX2, so no triiodo ketone with a leaving CIX3 can form.