JEE Main levelNumerical answerDifficulty 2 of 3bm174
Sucrose (CX12HX22OX11, molar mass 342gmol−1) has eight free hydroxyl groups. Assume all of them are acetylated by excess acetic anhydride and each -OH group consumes one molecule of (CHX3CO)X2O. How many moles of acetic anhydride are consumed by 171g of sucrose? (Give the answer as a number of moles, nearest integer.)
Numerical answer type, tolerance 0.5.
Answer: 4
Moles of sucrose = 171/342 = 0.5 mol. Each mole has 8 -OH groups, giving sucrose octaacetate, and each -OH uses one mole of acetic anhydride. Moles of acetic anhydride = 0.5 x 8 = 4.