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JEE Main levelSingle correct optionDifficulty 2 of 3bm171

Assertion (A): D-glucose does not give Schiff's test although it is an aldohexose. Reason (R): In solution glucose exists mainly as cyclic hemiacetal forms and contains only a trace of the free aldehyde form.

  1. ABoth A and R are true, and R is the correct explanation of A
  2. BBoth A and R are true, but R is not the correct explanation of A
  3. CA is true but R is false
  4. DA is false but R is true

Answer: A

The cyclic hemiacetal (pyranose) forms have no free CHO, so very little aldehyde is available to react with Schiff's reagent. Both statements are true and R explains A.
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