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JEE Main levelOne or more correct optionsDifficulty 2 of 3bm173

Which of the following pairs of sugars give the same osazone with excess phenylhydrazine?

  1. AD-glucose and D-fructose
  2. BD-glucose and D-mannose
  3. CD-glucose and D-galactose
  4. DD-mannose and D-fructose

Answer: A, B, D

Osazone formation uses C-1 and C-2 only, so sugars that have identical configuration at C-3, C-4 and C-5 give the same osazone. Glucose, mannose and fructose share C-3 to C-5; galactose differs at C-4, so it gives a different osazone.
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