JEE Advanced levelNumerical answerDifficulty 3 of 3bn034
An oxide of iron contains 72.4% Fe by mass (Fe =56, O =16). Find its simplest formula and then the AVERAGE oxidation number of iron in it (O is −2 and there is no peroxo link). Give the answer to two decimals.
Numerical answer type, tolerance 0.01.
Answer: 2.67
Moles: Fe =72.4/56=1.293 and O =27.6/16=1.725. The ratio Fe : O =0.75, so the formula is FeX3OX4. Then 3x+4(−2)=0 gives x=8/3=2.67.