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Structural Identification and Practical Organic Chemistry
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Estimation of elements: Lassaigne, Kjeldahl, Carius
JEE Main level
Single correct option
Difficulty 2 of 3
si181
In a Carius estimation, 0.32 g of an organic compound gave 0.453 g of
AgBr
. With Ag = 108 and Br = 80, the percentage of bromine in the compound is
A
81.32%
B
60.24%
C
104.86%
D
30.12%
Answer: B
Each mole of
AgBr
(188 g) contains 80 g of Br. Mass of Br =
188
80
×
0.453
=
0.1928
g, so %Br =
0.32
0.1928
×
100
=
60.24%
.
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