JEE Main levelSingle correct optionDifficulty 2 of 3si177
A compound containing C, N, S and Cl is fused with sodium. Before adding AgNOX3 to the sodium extract for the chlorine test, the extract is acidified with dilute HNOX3 and boiled. The purpose of boiling is to
Aoxidise ClX− to ClX2 so that it can be detected
Bconvert AgCl into the soluble [Ag(NHX3)X2]X+
Cexpel HCN and HX2S so that CNX− and SX2− do not precipitate with AgX+
Dconvert NaSCN into NaCN and sulphur
Answer: C
CNX− and SX2− would give AgCN and AgX2S with AgX+ and mask the white AgCl. Acidification converts them to volatile HCN and HX2S, which are driven off on boiling, leaving ClX− in solution.