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Structural Identification and Practical Organic Chemistry
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Difficulty 1 of 3
si176
2-Bromopropane is heated with aqueous KOH to give A. A is passed over heated copper at 573 K to give B. B is
A
propanone
B
propanal
C
propan-1-ol
D
propene
Answer: A
Aqueous KOH gives substitution: propan-2-ol (A). Dehydrogenation of a secondary alcohol over Cu at 573 K gives the ketone,
CH
X
3
COCH
X
3
, propanone.
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