NEET levelSingle correct optionDifficulty 1 of 3si041
In Lassaigne's test, the sodium extract of an organic compound containing nitrogen (but no sulphur) is boiled with FeSOX4 and then acidified with concentrated HX2SOX4. The colour obtained is
Ablood red
BPrussian blue
Cwhite precipitate
Dviolet
Answer: B
Sodium fusion converts C and N to NaCN. With FeSOX4 this gives hexacyanoferrate(II), which on acidification (Fe(III) formed) gives ferric ferrocyanide, Prussian blue. Blood red colour would need both N and S to be present.