JEE Advanced levelOne or more correct optionsDifficulty 3 of 3si043
Which reagents can be used to distinguish benzaldehyde from acetophenone? (more than one may be correct)
ATollens reagent
B2,4-DNP
CFehling's solution
DNaOH/IX2
Answer: A, D
Benzaldehyde reduces Tollens reagent while acetophenone does not. Acetophenone has CHX3COX− and gives iodoform with NaOH/IX2, while benzaldehyde does not. Fehling's solution is negative for both and both give 2,4-DNP derivatives.