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JEE Main levelSingle correct optionDifficulty 2 of 3si039

Sucrose gives a negative result with Benedict's solution, but gives a positive result when it is first boiled with dilute and then neutralised. The reason is that

  1. Asucrose is converted to a ketone
  2. Bhydrolysis gives glucose and fructose, which are reducing sugars
  3. Cacid oxidises sucrose to an aldehyde
  4. Dhydrolysis gives a non-reducing polysaccharide

Answer: B

In sucrose the anomeric carbons of glucose and fructose are joined through the glycosidic link, so no free aldehyde or hemiacetal group exists and it does not reduce Benedict's solution. Acid hydrolysis frees glucose and fructose, both of which are reducing.
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