JEE Advanced levelNumerical answerDifficulty 3 of 3so162
A 0.10M sucrose solution is hydrolysed 60% at 300K to glucose and fructose (CX12HX22OX11+HX2OCX6HX12OX6+CX6HX12OX6; assume no change in volume or in the amount of water). Using R=0.0821Latmmol−1K−1, calculate the osmotic pressure of the resulting solution in atm (two decimal places).
Numerical answer type, answer in atm, tolerance 0.01.
Answer: 3.94 atm
Sucrose left =0.10×0.40=0.040 M. Each reacted sucrose gives two monosaccharide molecules: 2×0.060=0.120 M. Total particles =0.160 M. π=0.160×0.0821×300=3.94 atm.