JEE Main levelNumerical answerDifficulty 2 of 3so027
An ideal solution of A and B has pA0=200torr and pB0=100torr. The vapour in equilibrium with it contains equal mole fractions of A and B (yA=0.5). Find the total vapour pressure of the solution in torr (two decimal places).
Numerical answer type, answer in torr, tolerance 0.01.
Answer: 133.33 torr
yA=pA/P=0.5 means pA=pB, i.e. 200xA=100(1−xA), so xA=1/3. Then P=200×31+100×32=133.33torr.