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Ionic solids: NaCl, CsCl, ZnS, CaF2, Na2O structures
NEET level
Single correct option
Difficulty 1 of 3
ss168
In zinc blende,
ZnS
, the sulphide ions form a ccp lattice and the
Zn
X
2
+
ions occupy
A
half of the octahedral voids
B
all the octahedral voids
C
all the tetrahedral voids
D
half of the tetrahedral voids
Answer: D
A ccp lattice of 4
S
X
2
−
ions has 8 tetrahedral voids. To match the formula
ZnS
only 4 of them are filled by
Zn
X
2
+
, i.e. half of the tetrahedral voids.
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