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NEET levelSingle correct optionDifficulty 1 of 3ss166

In the rock salt structure of , the coordination numbers of and are, respectively,

  1. A6 and 6
  2. B4 and 6
  3. C8 and 8
  4. D4 and 4

Answer: A

In NaCl each sits in an octahedral void of the ccp lattice, so it touches 6 ions, and by symmetry each touches 6 . The coordination numbers are 6 and 6.
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More questions on Ionic solids: NaCl, CsCl, ZnS, CaF2, Na2O structures