JEE Main levelSingle correct optionDifficulty 2 of 3ss170
An ionic solid MX has r+=95pm and r−=181pm. Using the radius ratio rule, the structure and the coordination number of the cation are
Atrigonal planar, 3
Boctahedral, 6
Ccubic, 8
Dtetrahedral, 4
Answer: B
The radius ratio r+/r−=95/181=0.525. This lies in the range 0.414 to 0.732, which corresponds to an octahedral arrangement, so the coordination number is 6.