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JEE Advanced levelSingle correct optionDifficulty 3 of 3ss123

In a spinel-type oxide the oxide ions form a ccp lattice. Cation occupies one-eighth of the tetrahedral voids and cation occupies one-half of the octahedral voids. The formula is

  1. A
  2. B
  3. C
  4. D

Answer: B

Per ion there are 2 tetrahedral and 1 octahedral void. ; per oxide. Multiplying by 4: , i.e. .
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