JEE Advanced levelSingle correct optionDifficulty 3 of 3ss123
In a spinel-type oxide the oxide ions form a ccp lattice. Cation A occupies one-eighth of the tetrahedral voids and cation B occupies one-half of the octahedral voids. The formula is
AAX2BOX4
BABX2OX4
CABOX2
DAX2BX2OX3
Answer: B
Per OX2− ion there are 2 tetrahedral and 1 octahedral void. A=2×81=41; B=1×21=21 per oxide. Multiplying by 4: A:B:O=1:2:4, i.e. ABX2OX4.