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JEE Advanced levelSingle correct optionDifficulty 3 of 3sb153

Caesium forms a stable superoxide in excess oxygen, whereas lithium gives only and is not obtained under normal conditions. The best explanation is:

  1. Acaesium has a higher first ionisation enthalpy than lithium and so oxidises oxygen further
  2. Bthe ion is smaller than and so fits better around
  3. Ca large cation is best able to stabilise the large ion in the crystal, while the small, strongly polarising favours the small with its much higher lattice energy
  4. Dlithium is not electropositive enough to transfer an electron to oxygen

Answer: C

Lattice energy depends on how well cation and anion sizes match. A large pairs with large and the lattice energy loss is small. The small polarises strongly, and the high lattice energy of (with ) wins. The other options are wrong: Cs has a lower ionisation enthalpy, and is larger than .
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