JEE Advanced levelSingle correct optionDifficulty 3 of 3sb151
11.2g of quicklime (CaO, molar mass 56gmol−1) is slaked completely with water. The resulting hydroxide is treated with excess chlorine at 313 K to form bleaching powder CaOClX2 (molar mass 127gmol−1) as per Ca(OH)X2+ClX2CaOClX2+HX2O, in 80% yield. The mass of CaOClX2 obtained is:
A25.40g
B12.70g
C16.26g
D20.32g
Answer: D
CaO+HX2OCa(OH)X2, and 11.2 g is 11.2/56=0.2 mol, so 0.2 mol Ca(OH)X2 forms. The theoretical mass of CaOClX2 is 0.2×127=25.40 g. At 80% yield it is 25.40 ×0.8=20.32 g.