NEET levelSingle correct optionDifficulty 1 of 3ro263
The compound shown is treated with PCC in CHX2ClX2. Which structure is the product?
AStructure A
BStructure B
CStructure C
DStructure D
Answer: D
The compound is pentan-1-ol. PCC in anhydrous CHX2ClX2 stops the oxidation of a primary alcohol at the aldehyde, giving pentanal. The acid would need aqueous Cr(VI) such as Jones reagent, and a primary alcohol cannot give a ketone.