JEE Main levelNumerical answerDifficulty 2 of 3rx139
Use Mn = 55, O = 16 and molar volume 22.4L/mol at STP. MnOX2+4HClMnClX2+ClX2+2HX2O. A mixture of 17.4g of MnOX2 and 500mL of 1.2MHCl is heated. Find the volume of ClX2 evolved at STP in litres (two decimals), assuming complete reaction of the limiting reagent.
Numerical answer type, answer in L, tolerance 0.02.
Answer: 3.36 L
n(MnOX2)=17.4/87=0.20 mol; n(HCl)=0.5×1.2=0.60 mol, which can react with only 0.60/4=0.150 mol MnOX2. So HCl is limiting, giving 0.150 mol ClX2. Volume =0.150×22.4=3.36L.