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Critical constants and liquefaction
JEE Advanced level
Numerical answer
Difficulty 3 of 3
rg206
Nitrogen has
a
=
0.1358
Pa
m
6
mo
l
−
2
and
b
=
3.85
×
1
0
−
5
m
3
mo
l
−
1
. Using
R
=
8.314
J
K
−
1
mo
l
−
1
, the critical temperature in K (one decimal) is
Numerical answer type, answer in K, tolerance 0.3.
Answer: 125.7 K
T
c
=
27
R
b
8
a
=
27
×
8.314
×
3.85
×
1
0
−
5
8
×
0.1358
=
8.64240
e
−
03
1.0864
=
125.71
K
, i.e.
125.7
K
. The experimental value is
126.2
K
.
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