JEE Advanced levelNumerical answerDifficulty 3 of 3rg085
The critical temperature of oxygen is 154K. Assuming van der Waals behaviour, its Boyle temperature in K (nearest integer) is
Numerical answer type, answer in K, tolerance 1.
Answer: 520 K
Tc=8a/27Rb and TB=a/Rb, so TB=827Tc=827×154=519.75K, i.e. 520K. The experimental Boyle temperature of oxygen (405K) is lower because real gases are not exactly van der Waals.