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JEE Advanced levelSingle correct optionDifficulty 3 of 3rg087

For liquefying hydrogen by the Linde process the gas must first be pre-cooled with liquid nitrogen. The reason is that

  1. Ahydrogen has a very high critical pressure
  2. Bthe inversion temperature of hydrogen (about ) is below room temperature, so throttling at room temperature would heat it
  3. Chydrogen reacts with the throttle valve at room temperature
  4. Dnitrogen dissolves in hydrogen and lowers its boiling point

Answer: B

Joule-Thomson cooling occurs only below the inversion temperature. For hydrogen , so at expansion through a valve warms the gas. Pre-cooling to about with liquid nitrogen brings it below so that subsequent throttling cools it to liquefaction.
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