JEE Main levelSingle correct optionDifficulty 2 of 3qc026
SnClX2 solution is added dropwise to HgClX2 solution, and then in large excess. The sequence observed is
Ared HgIX2, then yellow HgO
Bwhite silky HgX2ClX2, which turns grey due to Hg
Cgrey Hg first, then white HgX2ClX2
Dno change at any stage
Answer: B
SnClX2+2HgClX2SnClX4+HgX2ClX2 gives a white silky precipitate. Excess stannous chloride then reduces it further: SnClX2+HgX2ClX2SnClX4+2Hg, giving a grey precipitate of mercury.