JEE Main levelSingle correct optionDifficulty 2 of 3qc018
A white crystalline precipitate forms when NaX2HPOX4 is added to a solution containing NHX4Cl and excess NHX4OH (after groups I to V have been removed). The precipitate is
AMg(NHX4)POX4
BMg(OH)X2
CCaX3(POX4)X2 only
DAl(OH)X3
Answer: A
MgX2++NHX4X++HPOX4X2−+OHX−Mg(NHX4)POX4+HX2O, magnesium ammonium phosphate, is the group VI confirmation. Under these conditions Mg(OH)X2 is held in solution by NHX4Cl, and AlX3+ was removed in group III.