JEE Main levelSingle correct optionDifficulty 2 of 3qc019
The test for NHX4X+ is always performed on a fresh portion of the original solution, not on the filtrates, because
ANHX4X+ gives no reaction with NaOH after group separation
Bammonium salts are added as reagents (NHX4Cl, NHX4OH, (NHX4)X2COX3) during the scheme
CNHX4X+ is precipitated in group I
DNHX4X+ is destroyed by HX2S
Answer: B
Ammonium salts are used as group reagents in groups III to V, so NHX4X+ found later would be an artefact. Heating the original solution with NaOH liberates NHX3 (litmus test) or gives a brown colour with Nessler reagent.