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JEE Main levelSingle correct optionDifficulty 2 of 3qc015

is reported both in group I and in group II because

  1. A is soluble in dilute , so it appears in group I
  2. B is amphoteric and dissolves in excess only
  3. C exists in two oxidation states in solution, each belonging to a different group
  4. D is appreciably soluble in cold water, so precipitation in group I is incomplete and the rest is precipitated as in group II

Answer: D

has a fairly large (of the order of ), so some stays in the filtrate after dilute . That remainder gives black with in acid, because is extremely insoluble.
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