JEE Main levelSingle correct optionDifficulty 2 of 3qc015
PbX2+ is reported both in group I and in group II because
APbS is soluble in dilute HCl, so it appears in group I
BPbClX2 is amphoteric and dissolves in excess HCl only
CPbX2+ exists in two oxidation states in solution, each belonging to a different group
DPbClX2 is appreciably soluble in cold water, so precipitation in group I is incomplete and the rest is precipitated as PbS in group II
Answer: D
PbClX2 has a fairly large Ksp (of the order of 10−5), so some PbX2+ stays in the filtrate after dilute HCl. That remainder gives black PbS with HX2S in acid, because PbS is extremely insoluble.