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JEE Main levelSingle correct optionDifficulty 2 of 3qc012

Group II cations are precipitated by passing into the solution made about in . The role of the is to

  1. Aform soluble chloro-complexes of all group IV cations
  2. Braise so that all sulphides precipitate
  3. Cconvert completely into
  4. Dlower through the common ion effect of on ionisation, so only very insoluble sulphides precipitate

Answer: D

is shifted to the left by from , so falls to about . Only sulphides with extremely small (group II) exceed their solubility product; , , and stay in solution.
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