JEE Main levelSingle correct optionDifficulty 2 of 3qc012
Group II cations are precipitated by passing HX2S into the solution made about 0.3M in HCl. The role of the HCl is to
Aform soluble chloro-complexes of all group IV cations
Braise [SX2−] so that all sulphides precipitate
Cconvert HX2S completely into S
Dlower [SX2−] through the common ion effect of HX+ on HX2S ionisation, so only very insoluble sulphides precipitate
Answer: D
HX2S2HX++SX2− is shifted to the left by HX+ from HCl, so [SX2−] falls to about 10−21M. Only sulphides with extremely small Ksp (group II) exceed their solubility product; ZnS, NiS, CoS and MnS stay in solution.