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JEE Advanced levelSingle correct optionDifficulty 3 of 3pl245

A short fragment of a polyamide chain (three repeat units, end groups shown) is drawn. It is a fibre. Which statement about the forces between neighbouring chains, and the resulting class, is correct?

  1. ADipole forces between ester groups; a thermosetting polymer
  2. BCovalent crosslinks between chains; a thermosetting polymer
  3. CHydrogen bonding between N-H and C=O of neighbouring chains; a fibre
  4. DOnly weak van der Waals forces; an elastomer

Answer: C

The fragment is nylon 6 with many amide groups. The N-H of one chain hydrogen-bonds to the C=O of a neighbouring chain, giving strong, regular intermolecular attraction, which is characteristic of fibres. Weak van der Waals forces would give an elastomer, and a thermosetting polymer requires covalent crosslinks, which are not present here.
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