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JEE Advanced levelOne or more correct optionsDifficulty 3 of 3pl248

The cyclic compound shown is heated with a small amount of water to bring about polymerisation. Select all correct statements.

  1. AThe product is a polyamide
  2. BNo small molecule is eliminated in the ring-opening propagation steps
  3. CThe repeat unit contains six CH2 groups
  4. DThe product contains ester links

Answer: A, B

Caprolactam opens by ring-opening polymerisation to give nylon 6, a polyamide, and no small molecule is eliminated in the ring-opening propagation steps. The repeat unit is -NH-(CH2)5-CO-, with five CH2 groups (the ring has six carbons, one being the carbonyl carbon), and the links are amides, not esters. So statements A and B are correct, and C and D are wrong.
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