MolSynapsequestion bank
MolSynapse / Question bank / Polymers / Monomer from drawn repeat unit
JEE Advanced levelSingle correct optionDifficulty 3 of 3pl231

A short fragment of a biodegradable polyester chain (three repeat units, end groups shown) is drawn. It is formed by two different hydroxy acids. Cleaving every ester bond with water would give which pair of compounds, shown as two molecules among the structures?

  1. AStructure A
  2. BStructure B
  3. CStructure C
  4. DStructure D

Answer: C

Each unit has the O-CH(R)-CH2-C(=O) pattern, so the monomers are 3-hydroxy acids; the R groups are CH3 and C2H5. The polymer is PHBV, poly(3-hydroxybutyrate-co-3-hydroxyvalerate), and hydrolysis of the two ester bonds returns 3-hydroxybutanoic acid and 3-hydroxypentanoic acid. The 2-hydroxy, 3-hydroxyhexanoic and 4-/5-hydroxy pairs would place the hydroxyl at the wrong carbon or give a different chain length.
Practice Polymers More on Monomer from drawn repeat unit

More questions on Monomer from drawn repeat unit