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JEE Main levelSingle correct optionDifficulty 2 of 3pl230

A short fragment of a polymer chain (one repeat unit with its two end groups shown) is drawn. Which pair of monomers, shown as two molecules among the structures, gives this condensation polymer?

  1. AStructure A
  2. BStructure B
  3. CStructure C
  4. DStructure D

Answer: D

The chain contains ester links between a 1,4-benzenedicarbonyl unit and a two-carbon diol unit, so it is poly(ethylene terephthalate), PET (terylene, dacron). It forms from terephthalic acid (benzene-1,4-dicarboxylic acid) and ethylene glycol with loss of water. Phthalic acid would give the glyptal-type ortho ring, isophthalic acid a meta ring, and propane-1,3-diol a three-carbon diol unit.
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