JEE Advanced levelSingle correct optionDifficulty 3 of 3pl179
A copolymer chain contains acrylonitrile (CHX2=CH−CN) and buta-1,3-diene (CHX2=CH−CH=CHX2) units in the mole ratio 1 : 2 (end groups ignored; C 12, H 1, N 14). The mass percentage of nitrogen in the copolymer is
A17.5
B26.4
C13.1
D8.7
Answer: D
Acrylonitrile unit CX3HX3N = 53; butadiene unit CX4HX6 = 54. One acrylonitrile plus two butadiene units has mass 161 and contains 14 of nitrogen: 8.7 percent. The other values come from using ratio 1:1, ratio 2:1 or pure acrylonitrile.