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JEE Advanced levelSingle correct optionDifficulty 3 of 3pl186

Two polystyryl radicals, each ending in with the unpaired electron on the carbon bearing the phenyl group, terminate by disproportionation. The products are

  1. Atwo dead chains, both ending in
  2. Btwo dead chains, one ending in and the other in
  3. Ctwo dead chains, both ending in
  4. Done dead chain joined through a new bond between the two radical carbons

Answer: B

In disproportionation one radical abstracts a hydrogen atom from the next to the radical centre of the other. The abstracting chain becomes saturated () and the donor becomes unsaturated (). Two chains result, unlike combination, which gives one.
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