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JEE Advanced levelSingle correct optionDifficulty 3 of 3pl180

A PHBV chain contains 90 mol percent 3-hydroxybutanoate units () and 10 mol percent 3-hydroxypentanoate units (). Taking C 12, H 1, O 16 and ignoring end groups, how many 3-hydroxypentanoate units does a chain of molar mass 131100 g/mol contain?

  1. A150
  2. B1311
  3. C1524
  4. D1350

Answer: A

Unit masses are 86 and 100, so the average unit mass is 0.90 x 86 + 0.10 x 100 = 87.4. Number of units = 131100/87.4 = 1500. Ten percent of these are 3-hydroxypentanoate: 150.
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