JEE Advanced levelSingle correct optionDifficulty 3 of 3pl110
Nylon 2-nylon 6 has a repeat unit −[NH−CHX2−CO−NH−(CHX2)X5−CO]X− of molar mass 170 g/mol and contains two amide bonds per repeat unit. The mass of water needed to hydrolyse every amide bond in 85.0g of the polymer (end groups neglected; H2O = 18) is
A9.0 g
B18.0 g
C36.0 g
D27.0 g
Answer: B
85.0 g / 170 = 0.500 mol of repeat units, each with 2 amide bonds, so 1.00 mol of bonds needs 1.00 mol of water = 18.0 g.