JEE Advanced levelSingle correct optionDifficulty 3 of 3pl108
Nylon 2-nylon 6 is made from glycine and 6-aminohexanoic acid, HX2N−(CHX2)X5−COOH (131 g/mol), in 1 : 1 ratio. The repeat unit −[NH−CHX2−CO−NH−(CHX2)X5−CO]X− has a mass of 170 g/mol. Neglecting end groups and assuming complete conversion, the mass of 6-aminohexanoic acid needed for 1.70 kg of polymer is
A1130 g
B1081 g
C1700 g
D1310 g
Answer: D
1700/170 = 10.0 mol of repeat units, each using one 6-aminohexanoic acid: 10.0 x 131 = 1310 g. The 1081 g option wrongly splits the polymer mass in the ratio of the monomer masses, ignoring the water lost.