JEE Advanced levelSingle correct optionDifficulty 3 of 3pl109
A PHBV chain contains HB and HV units in a 4 : 1 mole ratio. HB is −[O−CH(CHX3)−CHX2−CO]X− (86 g/mol) and HV is −[O−CH(CX2HX5)−CHX2−CO]X− (100 g/mol). Neglecting end groups, the mass percent of HV units in the chain is closest to
A22.5
B20.0
C29.4
D25.0
Answer: A
For 5 units: mass = 4(86) + 100 = 444 g. HV percent = 100/444 x 100 = 22.5. The 20.0 value is the mole percent, not the mass percent.