JEE Main levelSingle correct optionDifficulty 2 of 3pt086
The ions SX2−, ClX−, KX+ and CaX2+ all have the configuration (1s)2(2s,2p)8(3s,3p)6 and Slater Z∗ values (for a 3p electron) of 4.75, 5.75, 7.75 and 8.75 respectively (in that order). Their radii therefore follow:
ACaX2+>KX+>ClX−>SX2−
BSX2−>ClX−>KX+>CaX2+
CClX−>SX2−>KX+>CaX2+
DSX2−>KX+>ClX−>CaX2+
Answer: B
With the same number of electrons and shells, a larger Z∗ pulls the cloud in more strongly. Z∗ rises from 4.75 (SX2−) to 8.75 (CaX2+), so the radius falls in the same direction.