JEE Main levelSingle correct optionDifficulty 2 of 3pt085
Which statement correctly describes a consequence of the lanthanoid contraction?
ALuX3+ is larger than LaX3+
Bthe second and third transition series differ greatly in atomic radii
CLa(OH)X3 is more basic than Lu(OH)X3 because LaX3+ is larger and polarises the OHX− group less
DLu(OH)X3 is more basic than La(OH)X3
Answer: C
Ln3+ radii decrease from La to Lu, so charge density and covalent character of Ln-OH rise. Hence basic strength of the hydroxides falls from La(OH)X3 to Lu(OH)X3.