JEE Main levelSingle correct optionDifficulty 2 of 3ph215
Which set of conditions is used to obtain mainly XeFX6 from xenon and fluorine?
AXe : FX2 = 1 : 5, about 873K, 7 bar
BXe in excess, about 673K, nickel vessel
CXe : FX2 = 1 : 20, about 573K, 60-70 bar
DXe : FX2 = 1 : 1, room temperature, 1 bar
Answer: C
A large excess of FX2 (about 20 mol per mol Xe) at about 573K and 60-70 bar gives XeFX6. A 1:5 ratio at 873 K and 7 bar gives XeFX4. Excess xenon (Xe : FX2 = 2 : 1) in a nickel tube at about 673 K gives XeFX2.