JEE Advanced levelSingle correct optionDifficulty 3 of 3ph212
XeFX4 disproportionates in water: 6XeFX4+12HX2O4Xe+2XeOX3+24HF+3OX2. If 0.60 mol of XeFX4 reacts completely, and XeOX3 and HF stay in solution, the number of moles of gas (Xe and OX2) evolved is
A0.40
B0.30
C0.70
D0.90
Answer: C
For 6 mol XeFX4 the gases are 4 mol Xe plus 3 mol OX2, which is 7 mol. For 0.60 mol, the scale factor is 0.60/6=0.10, so gases =0.10×7=0.70mol. The other products, XeOX3 and HF, remain dissolved.