JEE Advanced levelSingle correct optionDifficulty 3 of 3ph104
Given E∘(ClX2/ClX−)=1.36V and E∘(FeX3+/FeX2+)=0.77V, and F=96500Cmol−1, the standard Gibbs energy change for ClX2+2FeX2+2ClX−+2FeX3+ (per mole of ClX2) is
A+113.9kJ
B−113.9kJ
C−227.7kJ
D−56.9kJ
Answer: B
Ecell∘=1.36−0.77=0.59V. The balanced equation transfers n=2 electrons per ClX2. ΔG∘=−nFE∘=−2×96500×0.59=−113.9kJ (negative, so the reaction is spontaneous).