JEE Advanced levelOne or more correct optionsDifficulty 3 of 3ph107
Which of the following statements about the reactions of chlorine with sodium hydroxide are correct?
ABoth reactions are disproportionation reactions.
BWith cold dilute NaOH, chlorine is converted to oxidation states −1 and +1.
CIn both reactions chlorine acts only as an oxidising agent.
DWith hot concentrated NaOH, chlorine is converted to oxidation states −1 and +5.
Answer: A, B, D
Cold dilute: ClX2ClX−+OClX− (0 to -1 and +1). Hot concentrated: ClX2ClX−+ClOX3X− (0 to -1 and +5). In each case the same element is both oxidised and reduced, so chlorine is both oxidant and reductant, not only an oxidising agent.