JEE Advanced levelSingle correct optionDifficulty 3 of 3ph103
21.3g of ClX2 is passed into hot concentrated NaOH so that all of it disproportionates to chloride and chlorate. Taking Na=23 and Cl=35.5, the mass of NaCl formed is
A29.25g
B14.62g
C5.85g
D17.55g
Answer: A
3ClX2+6NaOH5NaCl+NaClOX3+3HX2O. Moles of ClX2=21.3/71=0.30, so NaCl=0.30×5/3=0.50 mol. Mass =0.50×58.5=29.25g. (The value 17.55 g would be the cold, dilute NaOH result, where 1 mol NaCl forms per mol ClX2.)