JEE Advanced levelOne or more correct optionsDifficulty 3 of 3pn178
Concentrated nitric acid is allowed to act on various substances. Select the correct statement(s).
AIron becomes passive and does not dissolve.
BWhite phosphorus is oxidised to HX3POX4 with evolution of NOX2.
CSulphur is oxidised to HX2SOX4 with evolution of NOX2.
DCopper reacts to give Cu(NOX3)X2 and mainly NO.
Answer: A, B, C
Conc. HNOX3 oxidises PX4 to HX3POX4 and SX8 to HX2SOX4, itself reduced to NOX2. With copper, conc. acid gives NOX2 (the product is NO only with dilute acid). Iron is rendered passive by a protective oxide layer in conc. acid.